Kevin's wife Danielle Jonas, 35, and Nick's other half Priyanka Chopra Jonas, 39, also got the chance to savage their husbands.
Priyanka confessed that she would marry 38-year-old Thor hunk Chris Hemsworth if he ever became single.
She joked: "I wouldn't want to marry anyone else unless Chris Hemsworth suddenly became single."
Danielle, meanwhile, poked fun at snubbing her now-husband's advances.
She quipped: "I basically ignored him the whole time, which he loved because he said it reminded him of his mom."
The likes of Pete Davidson, Blake Shelton and John Legend also roasted the pop trio, and they even had a go at one another.
Ahead of the show hitting the streaming platform, Nick had joked: "I definitely booked therapy for Monday morning."
And Joe was particularly worried about what Sophie had planned.
Kevin said: "I've heard rumours of what Sophie has planned for you Joe and I don't even...
Joe added: "It's never good when comedians that are helping us and are part of it are coming up to me like, 'Oh man, good luck, brother.'
"I'm like, that's not what I want to hear before this thing!"